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SAFETY DATA SHEET | Revision Date 14.03.2021 |
| Version 6.1 |
according to Regulation (EC) No. 1907/2006 | Print Date 03.04.2021 |
| GENERIC EU MSDS - NO COUNTRY SPECIFIC DATA - NO OEL DATA |
SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1 Product identifiers
Product name | : | Dimidium bromide for surfactant tests |
Product Number | : | 1.12130 |
Catalogue No. | : | 112130 |
Brand | : | Millipore |
REACH No. | : A registration number is not available for this substance as the | |
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| substance or its uses are exempted from registration, the |
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| annual tonnage does not require a registration or the |
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| registration is envisaged for a later registration deadline. |
CAS-No. | : 518-67-2 | |
1.2 Relevant identified uses of the substance or mixture and uses advised against
Identified uses : Reagent for analysis
1.3 Details of the supplier of the safety data sheet
Company | : | Merck KGaA | |
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| Frankfurter Str. 250 | |
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| D-64271 DARMSTADT | |
Telephone | : | +49 | (0)6151 72-0 |
Fax | : | +49 | 6151 727780 |
E-mail address | : | TechnicalService@merckgroup.com | |
1.4 Emergency telephone
Emergency Phone # : +(44)-870-8200418 (CHEMTREC (GB))
+(353)-19014670 (CHEMTREC Ireland)
001-803-017-9114 (CHEMTREC India)
SECTION 2: Hazards identification
2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008 Skin irritation (Category 2), H315 Eye irritation (Category 2), H319
Specific target organ toxicity - single exposure (Category 3), Respiratory system, H335 For the full text of the H-Statements mentioned in this Section, see Section 16.
2.2 Label elements
Labelling according Regulation (EC) No 1272/2008
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The life science business of Merck operates as MilliporeSigma in the US and Canada
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Signal word | Warning | |
Hazard statement(s) |
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H315 |
| Causes skin irritation. |
H319 |
| Causes serious eye irritation. |
H335 |
| May cause respiratory irritation. |
Precautionary statement(s) |
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P261 |
| Avoid breathing dust/ fume/ gas/ mist/ vapors/ spray. |
P264 |
| Wash skin thoroughly after handling. |
P271 |
| Use only outdoors or in a well-ventilated area. |
P280 |
| Wear protective gloves/ eye protection/ face protection. |
P302 | + P352 | IF ON SKIN: Wash with plenty of water. |
P305 | + P351 + P338 | IF IN EYES: Rinse cautiously with water for several minutes. |
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| Remove contact lenses, if present and easy to do. Continue |
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| rinsing. |
Supplemental Hazard | none | |
Statements |
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Reduced Labeling (<= 125 ml) | ||
Pictogram |
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Signal word | Warning | |
Hazard statement(s) | none | |
Precautionary | none | |
statement(s) |
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Supplemental Hazard | none | |
Statements |
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2.3 Other hazards
This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.
SECTION 3: Composition/information on ingredients |
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3.1 Substances |
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| Formula | : | C20H18BrN3 |
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| Molecular weight | : | 380,31 g/mol |
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| CAS-No. | : 518-67-2 |
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| EC-No. | : 208-256-7 |
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| Component |
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| Classification | Concentration | |
| 3,8-Diamino-5-methyl-6-phenylphenanthridinium bromide |
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| CAS-No. | 518-67-2 | Skin Irrit. 2; Eye Irrit. 2; | <= 100 % |
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| EC-No. | 208-256-7 | STOT SE 3; H315, H319, |
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| H335 |
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| For the full text of the H-Statements mentioned in this Section, see Section 16. | |||||
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The life science business of Merck operates as MilliporeSigma in the US and Canada
4.1 De script ion of first-aid measures
General advice
Show this material safety data sheet to the doctor in attendance.
If inhaled
After inhalation: fresh air.
In case of skin contact
In case of skin contact: Take off immediately all contaminated clothing. Rinse skin with water/ shower.
In case of eye contact
After eye contact: rinse out with plenty of water. Call in ophthalmologist. Remove contact lenses.
If swallowed
After swallowing: immediately make victim drink water (two glasses at most). Consult a physician.
4.2 Most important symptoms and effects, both acute and delay ed
The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in section 11
4.3 Indication of any immediate medical attention and special treatment needed No data available
SECTION 5: Firefighting measures
5.1 Extinguishing media
Suitable extinguishing media
Water Foam Carbon dioxide (CO2) Dry powder
Unsuitable extinguishing media
For this substance/mixture no limit ations of extinguishing agents are given.
5.2 Special hazards arising from the substance or mixture Carbon oxides
Nitrogen oxides (NOx)
Hydrogen bromide gas
Combustible.
Fire may cause evolution of:
hydrogen bromide, nitrogen oxides
Development of hazardous combustion gases or vapours possible in the event of fire.
5.3 Advice for firefighters
Stay in danger area only with self-contained breathing apparatus. Prevent skin contact by keeping a safe distance or by wearing suitable protective clothing.
5.4 Further information
Suppress (knock down) gases/vapors/mists with a water spray jet. Prevent fire extinguishing water from contaminating surface water or the ground water system.
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The life science business of Merck operates as MilliporeSigma in the US and Canada
SECTION 6: Accidental release measures
6.1 Personal precautions, protective equipment and emergency procedures
Advice for non-emergency personnel: Avoid inhalation of dusts. Avoid substance contact.
Ensure adequate ventilation. Evacuate the danger area, observe emergency procedures,
consult an expert.
For personal protection see section 8.
6.2 Environmental precautions
Do not let product enter drains.
6.3 Methods and materials for containment and cleaning up
Cover drains. Collect, bind, and pump off spills. Observe possible material restrictions (see sections 7 and 10). Take up dry. Dispose of properly. Clean up affected area. Avoid generation of dusts.
6.4 Reference to other sections
For disposal see section 13.
SECTION 7: Handling and storage
7.1 Precautions for safe handling
For precautions see section 2.2.
7.2 Conditions for safe storage, including any incompatibilities
Storage conditions
Tightly closed. Dry.
Recommended storage temperature see product label.
7.3 Specific end use(s)
Apart from the uses mentioned in section 1.2 no other specific uses are stipulated
SECTION 8: Exposure controls/personal protection 8.1 Control parameters
Ingredients with workplace control parameters 8.2 Exposure controls
Personal protective equipment
Eye/face protection
Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Safety glasses
Skin protection
This recommendation applies only to the product stated in the safety data sheet,
supplied by us and for the designated use. When dissolving in or mixing with other
substances and under conditions deviating from those stated in EN374 please
contact the supplier of CE-approved gloves (e.g. KCL GmbH, D-36124 Eichenzell,
Internet: www.kcl.de).
Full contact
Material: Nitrile rubber
Minimum layer thickness: 0,11 mm
Break through time: 480 min
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The life science business of Merck operates as MilliporeSigma in the US and Canada
Material tested:KCL 741 Dermatril® L
This recommendation applies only to the product stated in the safety data sheet,
supplied by us and for the designated use. When dissolving in or mixing with other
substances and under conditions deviating from those stated in EN374 please
contact the supplier of CE-approved gloves (e.g. KCL GmbH, D-36124 Eichenzell,
Internet: www.kcl.de).
Splash contact
Material: Nitrile rubber
Minimum layer thickness: 0,11 mm
Break through time: 480 min
Material tested:KCL 741 Dermatril® L
Body Protection
protective clothing
Respiratory protection
required when dusts are generated.
Our recommendations on filtering respiratory protection are based on the following
standards: DIN EN 143, DIN 14387 and other accompanying standards relating to
the used respiratory protection system.
Recommended Filter type: Filter type P2
The entrepeneur has to ensure that maintenance, cleaning and testing of respiratory protective devices are carried out according to the instructions of the producer. These measures have to be properly documented.
Control of environmental exposure
Do not let product enter drains.
SECTION 9: Physical and chemical properties
9.1 Information on basic physical and chemical properties
a) | Appearance | Form: solid |
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| Color: red brown |
b) | Odor | No data available |
c) | Odor Threshold | No data available |
d) | pH | No data available |
e) | Melting | Melting point/range: 230 °C |
| point/freezing point |
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f) | Initial boiling point | No data available |
| and boiling range |
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g) | Flash point | No data available |
h) | Evaporation rate | No data available |
i) | Flammability (solid, | No data available |
| gas) |
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j) | Upper/lower | No data available |
| flammability or |
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| explosive limit s |
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k) | Vapor pressure | No data available |
l) | Vapor density | No data available |
Millipore- 1.12130 | Page 5 of 9 | |
The life science business of Merck operates as MilliporeSigma in the US and Canada
n) Water solubility
No data available
p) | Autoignition | No data available |
| temperature |
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q) | Decomposition | No data available |
| temperature |
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r) | Viscosity | Viscosity, kinematic: No data available |
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| Viscosity, dynamic: No data available |
s) | Explosive properties | No data available |
t) | Oxidizing properties | No data available |
9.2 Other safety information | ||
| Bulk density | ca.380 kg/m3 |
SECTION 10: Stability and reactivity
10.1 Reactivity
The following applies in general to flammable organic substances and mixtures: in correspondingly fine distribution, when whirled up a dust explosion potential may generally be assumed.
10.2 Chemical stability
The product is chemically stable under standard ambient conditions (room temperature).
10.3 Possibility of hazardous reactions
Violent reactions possible with:
Strong oxidizing agents
10.4 Conditions to avoid
no information available
10.5 Incompatible materials
No data available
10.6 Hazardous decomposition products
In the event of fire: see section 5
SECTION 11: Toxicological information
11.1 Information on toxicological effects
Acute toxicity
No data available
Skin corrosion/irritation
No data available
Serious eye damage/eye irritation
No data available
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The life science business of Merck operates as MilliporeSigma in the US and Canada
Respiratory or skin sensitization
No data available
Germ cell mutagenicity
No data available
Carcinogenicity
IARC:
No ingredient of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC.
Reproductive toxicity
No data available
Specific target organ toxicity - single exposure Inhalation - May cause respiratory irritation.
Specific target organ toxicity - repeated exposure No data available
Aspiration hazard
No data available
11.2 Additional Information
Not available
To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.
SECTION 12: Ecological information
12.1 Toxicity
No data available
12.2 Persistence and degradability
No data available
12.3 Bioaccumulative potential
No data available
12.4 Mobility in soil
No data available
12.5 result s of PBT and vPvB assessment
This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.
12.6 Other adverse effects
No data available
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The life science business of Merck operates as MilliporeSigma in the US and Canada
SECTION 13: Disposal considerations
13.1 | Waste treatment methods |
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| See www.retrologistik.com for processes regarding the return of chemicals and | |||
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| containers, or contact us there if you have further questions. |
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| SECTION 14: Transport information |
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14.1 | UN number |
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| ADR/RID: - | IMDG: - | IATA: - | |
14.2 | UN proper shipping name |
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| ADR/RID: Not dangerous goods |
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| IMDG: | Not dangerous goods |
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| IATA: | Not dangerous goods |
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14.3 | Transport hazard class(es) |
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| ADR/RID: - | IMDG: - | IATA: - | |
14.4 | Packaging group |
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| ADR/RID: - | IMDG: - | IATA: - | |
14.5 | Environmental hazards |
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| ADR/RID: no | IMDG Marine pollutant: no | IATA: no | |
14.6 | Special precautions for user |
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Further information
Not classified as dangerous in the meaning of transport regulations.
SECTION 15: Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
This material safety data sheet complies with the requirements of Regulation (EC) No.
1907/2006.
National legislation
Seveso III: Directive 2012/18/EU of the European Parliament and of the Council on the control of major-accident hazards involving dangerous substances.
: Not applicable
Other regulations
Take note of Dir 94/33/EC on the protection of young people at work.
15.2 Chemical Safety Assessment
For this product a chemical safety assessment was not carried out
SECTION 16: Other information
Full text of H-Statements referred to under sections 2 and 3.
Millipore- 1.12130 Page 8 of9
The life science business of Merck operates as MilliporeSigma in the US and Canada
Causes skin irritation. | |
H319 | Causes serious eye irritation. |
H335 | May cause respiratory irritation. |
Further information
The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. Sigma-Aldrich Corporation and its Affiliates shall not be held liable for any damage result ing from handling or from contact with the above product. See www.sigma-aldrich.com and/or the reverse side of invoice or packing slip for additional terms and conditions of sale.
Copyright 2020 Sigma-Aldrich Co. LLC. License granted to make un limit ed paper copies for internal use only.
The branding on the header and/or footer of this document may temporarily not visually match the product purchased as we transition our branding. However, all of the information in the document regarding the product remains unchanged and matches the product ordered. For further information please contact mlsbranding@sial.com.
Millipore- 1.12130 Page 9 of9
The life science business of Merck operates as MilliporeSigma in the US and Canada
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